有機金屬銥錯合物及其簡易合成方法和用途
專利類型:
發明人:
Chia, Win-Long
Chen, Yung-Chi
專利起迄日期:
2021-11-11 to 2038-03-07
單位 :
化學系
申請國家:
德國
申請號 :
201810105179
公告日:
2021-11-11
公開/公告號:
102018105179 B4
發明連絡人 :
賈文隆副教授
連絡人電話 :
02-29053567
email:
027087@mail.fju.edu.tw
摘要:
Provided are an organometallic iridium complex, a synthetic method thereof, and an organic light emitting device using the same. The synthetic method comprises the following steps of: (a) making t-Bu-Ar^1-MgX react with a nitrogen-containing heteroaryl salt in a nucleophilic reaction, so as to obtain an intermediate, wherein t-Bu represents a tert-butyl group, Ar^1 is an arylene group having 5 to 16 carbon atoms or a sulfur-containing heteroarylene group having 4 to 14 carbon atoms, X is a halogen atom, the nitrogen-containing heteroaryl salt is a salt which includes the t-Bu-Ar^2 group, and Ar^2 is a nitrogen-containing heteroaryl group having 5 to 14 carbon atoms; (b) oxidizing the intermediate with an oxidant for aromatization to obtain a ligand; and (c) making the ligand react with an iridium (III) acetylacetonate to obtain the organometallic iridium complex. The organometallic iridium complex is represented by following formula (I).